In order to invoke screen-scraper from Python, screen-scraper needs to be running in server mode. If you'd like a refresher on how to start up screen-scraper in server mode go ahead and follow the link, then return here.
Your Python code will need to refer to screen-scraper's Python driver, called remote_scraping_session.py. You can find this file in the misc\python\ folder of your screen-scraper installation. You'll want to put a copy of the file into the directory where you plan on putting the Python file that will invoke screen-scraper.
Download the shopping.py file, then save it in the same directory where you copied the remote_scraping_session.py file. Rename the file from shopping.py.txt to shopping.py.
Run the command python shopping.py in your console. You'll be asked which keyword to search. Type in a product keyword, such as bug, then press the Enter key. If all goes well the program will take a little while to load (it's waiting as screen-scraper extracts the data), then it will output the corresponding products.
If that didn't go quite as you expected here are some things to check:
Assuming that test worked, fire up your favorite Python editor and open the shopping.py file in it. The file is pretty heavily commented, so hopefully it makes sense what's going on. If not, try reviewing the Python documentation or posting to our forum.
When you invoke screen-scraper as a server it creates log files corresponding to your scraping session in its log folder. Take a look in that folder for your Shopping Site log file and take a look through it. It should look similar to what you see when you run scraping sessions in the workbench.